Back to Search Start Over

Could ionic gamma-elimination be concerted: clocking the internal displacement across a cyclobutane ring

Authors :
Habusha, Uri
Rozental, Esther
Hoz, Shmaryahu
Source :
Journal of the American Chemical Society. Dec 18, 2002, Vol. 124 Issue 50, p15006, 6 p.
Publication Year :
2002

Abstract

The ability of a carbanion to displace the leaving group in a barrierless process is examined. It is found that the concerted nature of the reaction depends on the conditions used to generate the carbanion.

Details

Language :
English
ISSN :
00027863
Volume :
124
Issue :
50
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.123836172