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Tuning the metal-metal bonds in the linear tricobalt compound Co3(dpa)(sub 4)Cl2: bond-stretch and spin-state isomers
- Source :
- Inorganic Chemistry. March 12, 2001, Vol. 40 Issue 6, p1256, 9 p.
- Publication Year :
- 2001
-
Abstract
- The structural and magnetic behavior of a greater range of solvated crystals of Co(sub 3)(dpa)(sub 4)Cl2, including the temperature dependences of both structures and magnetism are determined. The magnetic susceptibility measurements from 1.8 to 350 K indicate in each case that a gradual spin crossover, from a doublet to a quartet state, occurs over this temperature range.
- Subjects :
- Spin coupling -- Research
Metal bonding -- Research
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 40
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.124051186