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Synthesis, structure and multi-NMR studies of (Me(sub 4)N)[A{M(SC{O}Ph)-(sub 3}(sub 2] (A=Na, M=Hg; A=K, M=Cd or Hg)

Authors :
Deivaraj, Theivanayagam
Dean, Philip A.
Vittal, Jagadese J.
Source :
Inorganic Chemistry. July 10, 2000, Vol. 39 Issue 14, p3071, 4 p.
Publication Year :
2000

Abstract

The compounds (Me(sub 4)N)[A{M(SC{O}Ph)-(sub 3}(sub 2] were synthesized by reacting appropriate metal chloride and the structures were determined by single-crystal X-ray defraction method. Solution metal NMR studies showed the concentration-dependent dissociation of the alkali metal ions in the trinuclear anions.

Details

Language :
English
ISSN :
00201669
Volume :
39
Issue :
14
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.124118438