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Structural dependence of thermodynamics of alkene binding to Yttrium alkyl complexes and of kinetics of alkyl migration to coordinated alkenes

Authors :
Casey, Charles P.
Tunge, Jon A.
Ting-Yu Lee
Fagan, Maureen A.
Source :
Journal of the American Chemical Society. March 5, 2003, Vol. 125 Issue 9, p2641, 11 p.
Publication Year :
2003

Abstract

Agostic interactions in yttrium alkyls are structure dependent. Processes related to chain transfer and site epimerization at the metal center are reported.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
9
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.124452448