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Gas -phase SN2 and bromine abstraction reactions of chloride ion with bromomethane: Reaction cross sections and energy disposal into products

Authors :
Angel, Laurence A.
Erwin, Kent M.
Source :
Journal of the American Chemical Society. Jan 29, 2003, Vol. 125 Issue 4, p1014, 14 p.
Publication Year :
2003

Abstract

The reaction cross-sections and the speed of product distribution are specified for the bimolecular gas phase nucleophilic substitution (SN2) reaction as a function of collided force. The outcome indicates that the exothermic SN2 reaction is not sufficient in comparison to the phasespace theory along with the ion dipole capture models.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
4
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.124640023