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Aromatic gold and silver 'rings': Hydrosilver(I) and hydrogold(I) analogues of aromatic hydrocarbons

Authors :
Tsipis, Constantinos A.
Karagiannis, Eustathios E.
Kladou, Panagiota F.
Tsipis, Athanassios C.
Source :
Journal of the American Chemical Society. Oct 13, 2004, Vol. 126 Issue 40, p12916, 14 p.
Publication Year :
2004

Abstract

The aromaticity of the hydrosilver(I) and hydrogold(I) analogues of aromatic hydrocarbons is verified by a number of established criteria of aromaticity, such as structural, energetic, magnetic, and chemical criteria. The comprehensive study of the structural, energetic, spectroscopic, and bonding properties of the novel classes of inorganic compounds containing bonds that are characterized by a common ring-shaped electron density, more commonly seen in organic molecules, is presented.

Details

Language :
English
ISSN :
00027863
Volume :
126
Issue :
40
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.124756751