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Pulse radiolysis study on the estimation of radiolytic yields of water decomposition products in high-temperature and supercritical water: Use of methyl viologen as a scavenger

Authors :
Lin, Mingzhang
Katsumura, Yosuke
Muroya, Yusa
Hui He
Guozhong Wu
Han, Zhenhu
Miyazaki, Toyoaki
Kudo, Hisaaki
Source :
Journal of Physical Chemistry A. Oct 7, 2004, Vol. 108 Issue 40, p8287, 9 p.
Publication Year :
2004

Abstract

Methyl viologen (1,1-dimethyl-4-4-bipyridinium dichloride) is used as a scavenger to estimate the radiolytic yields of water decomposition products from room temperature to 400 degree Celsius by pulse radiolysis method. {G(e(sub aq)(super -) + G(OH) + G(H)} is studied using a 0.5 mM MV(super 2+) solution in the presence of 10 mM NaCOOH up to 200 degree Celsius and in the presence of 0.2 M ethanol up to 400 degree Celsius.

Details

Language :
English
ISSN :
10895639
Volume :
108
Issue :
40
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.124841020