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Asymmetric synthesis of syn- and anti-1,3-amino alcohols

Authors :
Kochi, Takuya
Tang, Tony P.
Ellman, Jonathan A.
Source :
Journal of the American Chemical Society. June 12, 2002, Vol. 124 Issue 23, p6518, 2 p.
Publication Year :
2002

Abstract

The stereoselective synthesis of both the syn- and anti-1,3-amino alcohols from a common synthetic intermediate is depicted. The first application of metalloenamines derived from N-sulfinyl imines is reported for the highly diastereoselective addition to aldehydes.

Details

Language :
English
ISSN :
00027863
Volume :
124
Issue :
23
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.125033291