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Synthetic and structural studies on [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 6-x)](Super x-) as active site models for Fe-only hydrogenases
- Source :
- Journal of the American Chemical Society. Dec 19, 2001, Vol. 123 Issue 50, p12518, 10 p.
- Publication Year :
- 2001
-
Abstract
- A range of derivatives of the type [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 4)] (Super 2-) can be prepared by CN-for -CO substitution reactions. These syntheses occur for alkyl- and arylthiolato derivatives and for alkyldithiolates. The products are stable and have been fully characterized by X-ray diffraction for three derivatives.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 123
- Issue :
- 50
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.125135623