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Bis(dialkylamide)hydrogen dibromobromate precursors of hypobromite ion in reactions with nerve and blister agent simulants
- Source :
- Journal of Organic Chemistry. Dec 24, 2004, Vol. 69 Issue 26, p9238, 3 p.
- Publication Year :
- 2004
-
Abstract
- Bis(dialkylamide)hydrogen dibromobromate is used as a source of BrO(super -), and is shown that rates of dephosphorylation are similar with BrO(super -) generated from these complexes or from Br2-H2O. Reactions of 4-nitrophenyl tosylate, with BrO(super -) are rapid with 0.1 M BrO(super -), under conditions in which oxidations of organic sulfides are too fast to be followed by conventional methods.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 69
- Issue :
- 26
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.127675130