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Role of the transition metal in metallaborane chemistry. Reactivity of (Cp(super *)ReH2)2B4H4 with BH3.thf, CO and Co2(CO)8

Authors :
Ghosh, Sundargopal
Xinjian Lei
Maoyu Shang
Fehlner, Thomas P.
Source :
Inorganic Chemistry. Nov 13, 2000, Vol. 39 Issue 23, p5373, 10 p.
Publication Year :
2000

Abstract

The formation of (Cp(super *)ReH2)2B4H4(2) from Cp(super *)ReCl4 and its reaction with BH3.thf, CO and Co2(CO)8 are described. The characterizations of intermediates reveal mechanistic details.

Details

Language :
English
ISSN :
00201669
Volume :
39
Issue :
23
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.127834437