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Planar tetra-, penta-, hexa-, hepta-, and octacoordinate silicons: A universal structural pattern
- Source :
- Journal of the American Chemical Society. Dec 15, 2004, Vol. 126 Issue 49, 16227-16231
- Publication Year :
- 2004
-
Abstract
- A universal structural pattern is presented at density functional theory level to incorporate planar tetra-, penta-, hexa-, hepta-, and octacoordinate silicons in C2vBnE2Si series. The structural pattern could be applied to form other planar coordinate nonmetals including Ge, P, As, Al, and Ga, which needs to be confirmed in experiments to open a new branch of chemistry on planar coordinate main group elements.
- Subjects :
- Density functionals -- Analysis
Silicon -- Structure
Silicon -- Spectra
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 126
- Issue :
- 49
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.129137110