Rapid fixation of methylene chloride by a macrocyclic amine

Authors :: Jung-Jae Lee
Smith, Bradley D.
Stanger, Keith J.
Noll, Bruce C.
Gonzalez, Carlos
Marquez, Manuel
Source :: Journal of the American Chemical Society. March 30, 2005, Vol. 127 Issue 12, 4184-4185
Publication Year :: 2005
Abstract: The simple macrocyclic amine attacking methylene chloride with unprecedented high reactivity to give quaternary ammonium salt is described. Methylene chloride is a volatile but relatively inert organic liquid that is used extensively as a solvent in small and large-scale synthesis and extraction processes.

Subjects :: Ammonium chloride -- Chemical properties
Ammonium compounds -- Chemical properties
Ammonium paratungstate -- Chemical properties
Methylene chloride -- Chemical properties
Chemistry

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