Synthesis of planar chiral phosphapalladacycles by highly enantioselective transcyclopalladation

Authors :: Roca, Francesc X.
Motevalli, Majid
Richards, Christopher J.
Source :: Journal of the American Chemical Society. March 2, 2005, Vol. 127 Issue 8, 2388-2
Publication Year :: 2005
Abstract: The reaction between different metallocenes as a means of achieving the first highly enantioselective synthesis of planar chiral phosphapalladacycles is discussed. Chiral phosphpalladacycles are available in high enantioselectivity by utilizing oxazolines as recoverable palladium transfer reagents.

Subjects :: Oxazoles -- Chemical properties
Palladium -- Chemical properties
Chemical synthesis -- Research
Chemistry

Tools