Hydroxylamines as oxygen atom nucleophiles in transition-metal-catalyzed allylic substitution

Authors :: Miyabe, Hideto
Yoshida, Kazumasa
Takemoto, Yoshiji
Yamauchi, Masashige
Source :: Journal of Organic Chemistry. March 18, 2005, Vol. 70 Issue 6, p2148, 6 p.
Publication Year :: 2005
Abstract: The viability of hydroxylamines as nucleophiles in transition-metal-catalyzed allylic substitution was examined. It was found that the oxygen atom of hydroxylamines having an N-electron-withdrawing substituent acts as a reactive nucleophile.

Subjects :: Nucleophilic reactions -- Research
Nitrogen compounds -- Electric properties
Biological sciences
Chemistry

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