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Metal ion catalysis of natural products transformations. Novel aldopentose disproportionation reactions catalyzed by rhodium(III)
- Source :
- Inorganic Chemistry. March 21, 2005, Vol. 44 Issue 6, p1950, 5 p.
- Publication Year :
- 2005
-
Abstract
- The detailed stoichiometry of the reaction between the aldopentoses, ribose, arabinose, lyxose, and xylose, and the cis rhodium(III) complex of the macrocyclic tetraamine ligand rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane in weakly acidic aqueous solution is studied by (super 13)C NMR, using deuterium- and carbon-13-labeled substrates.
- Subjects :
- Rhodium -- Chemical properties
Metal ions -- Research
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.132863149