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Remote substituent effects upon the rearrangements of housane cation radicals

Authors :
Gerken, James B.
Wang, Selina C.
Preciado, Alejandro B.
Park, Young Sam
Little, R. Daniel
Nishiguchi, Gisele
Tantillo, Dean J.
Source :
Journal of Organic Chemistry. June 10, 2005, Vol. 70 Issue 12, p4598, 11 p.
Publication Year :
2005

Abstract

The rearrangement of a series of housane-derived cation radicals is investigated. The results indicate that it is possible to influence the direction of migration in housane-derived cation radical rearrangements even when the regiochemical control unit is not directly appended to the migration terminus.

Details

Language :
English
ISSN :
00223263
Volume :
70
Issue :
12
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.135328822