Back to Search Start Over

Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent

Authors :
Wei Xu
Dolbier, William R., Jr.
Source :
Journal of Organic Chemistry. June 10, 2005, Vol. 70 Issue 12, p4741, 5 p.
Publication Year :
2005

Abstract

The scope and limitations of the CF3I/TDAE reagent in nucleophilic trifluoromethylation chemistry is studied. It is demonstrated that a two-electron transfer from TDAE to CF3I generates a stabilized TDAE dication/trifluoromethyl anion 'complex'.

Subjects

Subjects :
Nucleophilic reactions -- Research
Schiff bases -- Chemical properties
Methylation -- Research
Biological sciences
Chemistry

Details

Language :
English
ISSN :
00223263
Volume :
70
Issue :
12
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.135328930

Tools

Authors Abstract Subjects Details