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M5H5X (M = Ag, Au, Pd Pt; X = Si, Ge, P, S): Hydrometal pentagons with D5h planar pentacoordinate nonmetal centers

Authors :
Si-Dian Li
Chang-Qing Miao
Source :
Journal of Physical Chemistry A. August 25, 2005, Vol. 109 Issue 33, 7594-7597
Publication Year :
2005

Abstract

A density functional theory investigation on M5H5X hydrometal pentagons (M=Ag, Au, Pd Pt) with D5h planar pentacoordinate nonmetal centers (X = Si, Ge, P, S) is presented. The introduction of the nonmetal centers X introduces p aromaticity to M5H5X complexes.

Details

Language :
English
ISSN :
10895639
Volume :
109
Issue :
33
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.138926886