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Organo-tricyanoborates as tectons: Illustrative coordination polymers based on copper(I) derivatives
- Source :
- Inorganic Chemistry. Sept 5, 2005, Vol. 44 Issue 18, p6256, 9 p.
- Publication Year :
- 2005
-
Abstract
- The first systematic study on the use of tricyanoborates as ligands and also the use of the organoboran tricyanides as precursors to coordination polymers are described. The treatment of [PhB(CN)(sub 3)](super -) with [Cu(PCy3)(sub 2)(NCMe)(sub x)]PF6 has given the one-dimensional polymer [PhB(CN)(sub 3)Cu(PCy3)(Cub 2)], wherein two pf the three BCN substituents are coordinated.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 18
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.140933149