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Unique Co chemisorption properties of gold hexamer: Au6(CO)(sub n)-(n=0-3)
- Source :
- Journal of the American Chemical Society. August 31, 2005, Vol. 127 Issue 34, p12098, 9 p.
- Publication Year :
- 2005
-
Abstract
- A combined photoelectron spectroscopy (PES) and density functional theory (DFT) investigation of the CO chemisorption behavior on the gold hexamer from one to three CO groups Au6(CO)(sub n)-(n=0-3) is reported. While the electron donor capability of CO is known to decrease the electron binding energies of Aum(CO)(sub n)-complexes, CO chemisorption on Au6(CO)(sub n)-(n=1-3) is observed to have very little effect on the electron binding energies of the first PES band of Au6(CO)(sub n)-(n=1-3).
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 34
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.140983099