Back to Search
Start Over
Magnetic properties of isostructural dodecanuclear polyoxovanadates with six and eight vanadium(IV) ions
- Source :
- Inorganic Chemistry. May 12, 1993, Vol. 32 Issue 10, p2114, 4 p.
- Publication Year :
- 1993
-
Abstract
- The magnetic properties of two polyoxovanadate anions, (V12As8O40(HCO2))3- and (V12As8O40(HCO2))5- were investigated. The results suggest that in the former compound there are six vanadium(IV) and six vanadium(V) ions, while in the latter there are eight vanadium(IV) and four vanadium(V) ions. The electron paramagnetic resonance spectra of the two compounds show opposite behaviors at low and high fields, probably due to field-dependent relaxation effects.
- Subjects :
- Oxo compounds -- Analysis
Vanadium -- Magnetic properties
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 32
- Issue :
- 10
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.14110349