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Energetic quaternary salts containing bi(1,2,4-triazoles)

Energetic quaternary salts containing bi(1,2,4-triazoles)

Authors :
Hong Xue
Twamley, Brendan
Shreeve, Jean'ne M.
Source :
Inorganic Chemistry. Oct 3, 2005, Vol. 44 Issue 20, p7009, 5 p.
Publication Year :
2005

Abstract

The formation, structural, thermal and thermodynamic properties of the first quaternary salts of 4,4'-bi(1,2,4-triazole) or N-4-(1,2,4-triazole)-N-3-(4-methyl-1,2,4-triazole)amine by reaction with nitric or perchloric acid or 5-nitro-tetrazole are described. The melting points, thermal degradation temperatures and the standard heats of formation for compounds with perchlorate as the anion are found to be higher than those of the analogous nitrates, whereas the highest heats of formation are obtained when 5-nitro-tetrazolate is used as the energetic anion.

Details

Language :
English
ISSN :
00201669
Volume :
44
Issue :
20
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.142503939