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Energetic quaternary salts containing bi(1,2,4-triazoles)
Energetic quaternary salts containing bi(1,2,4-triazoles)
- Source :
- Inorganic Chemistry. Oct 3, 2005, Vol. 44 Issue 20, p7009, 5 p.
- Publication Year :
- 2005
-
Abstract
- The formation, structural, thermal and thermodynamic properties of the first quaternary salts of 4,4'-bi(1,2,4-triazole) or N-4-(1,2,4-triazole)-N-3-(4-methyl-1,2,4-triazole)amine by reaction with nitric or perchloric acid or 5-nitro-tetrazole are described. The melting points, thermal degradation temperatures and the standard heats of formation for compounds with perchlorate as the anion are found to be higher than those of the analogous nitrates, whereas the highest heats of formation are obtained when 5-nitro-tetrazolate is used as the energetic anion.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 20
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.142503939