Back to Search Start Over

Heterocyclic derivative syntheses by palladium-catalyzed oxidative cyclization-alkoxycarbonylation of substituted gamma-oxoalkynes

Authors :
Bacchi, Alessia
Costa, Mirco
Ca, Nicola Della
Gabriele, Bartolo
Salerno, Giuseppe
Cassoni, Silvia
Source :
Journal of Organic Chemistry. June 24, 2005, Vol. 70 Issue 13, p4971, 9 p.
Publication Year :
2005

Abstract

The heterocyclic ring formation by means of PdI2-catalyzed oxidative cyclization-alkoxycarbonylation reactions to aliphatic acetylenic ketones is investigated. It is found that cyclopentenone, dihydropyridinone and tetrahydropyridinedione derivatives, formed when the reaction is carried out at higher temperature and for a long time, can also be selectively obtained through an acid treatment of tetrahydrofuran and oxazoline derivatives.

Details

Language :
English
ISSN :
00223263
Volume :
70
Issue :
13
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.143427742