Experimental and computational studies on the mechanism of N-heterocycle C- activation by Rh(I)

Authors :: Wiedermann, Sean H.
Lewis, Jared C.
Ellman, Jonathan A.
Bergman, Robert G.
Source :: Journal of the American Chemical Society. Feb 22, 2006, Vol. 128 Issue 7, p2452, 11 p.
Publication Year :: 2006
Abstract: Evidence for a proposed mechanism of C-H activation of 3-methyl-3,4-dihydroquinazoline by (PCy3)(sub 2)RhCl is presented. The consequences of the mechanism for coupling reactions of N-heterocycles that occur through Rh-catalyzed C-H bond activation are discussed.

Subjects :: Rhodium -- Chemical properties
Chlorine compounds -- Chemical properties
Heterocyclic compounds -- Chemical properties
Chemistry

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