Synthesis of tetrasubstituted and functionalized enol ethers by e-selective olefination of esters with ynolates

Authors :: Shindo, Mitsuru
Kita, Taisuke
Kumagai, Toshihiro
Matsumoto, Kenji
Shishido, Kozo
Source :: Journal of the American Chemical Society. Feb 1, 2006, Vol. 128 Issue 4, 1062-1063
Publication Year :: 2006
Abstract: The stereocontrolled synthesis of multisubstituted and functionalized enol ethers through olefination is studied. It is noted that the development of first stereoselective olefination of esters affording tetrasubstituted, functionalized enol ethers are useful synthetic intermediates for various C-C bond formations.

Subjects :: Esters -- Structure
Esters -- Chemical properties
Esters -- Optical properties
Electrophiles -- Research
Chemistry

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