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Oxomolybdenum tetrathiolates with sterically encumbering ligands: Modeling the effect of a protein matrix on electronic structure and reduction potentials
- Source :
- Inorganic Chemistry. Nov 14, 2005, Vol. 44 Issue 23, 8216-8222
- Publication Year :
- 2005
-
Abstract
- The effect of sterically encumbering ligands on the electronic structure of three para-substituted oxomolybdenum tetrathiolate complexes was determined using spectroscopy techniques. The spectra show that the observed reduction potential differences in these complexes are not a result of changes in the electronic structure of the [MoOS(sub 4)](super -) site.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 23
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.144686977