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Synthesis and electrochemistry of undeca-substituted metallo-benzoylbiliverdins
- Source :
- Inorganic Chemistry. Feb 20, 2006, Vol. 45 Issue 4, 1463-1470
- Publication Year :
- 2006
-
Abstract
- Three metallo-benzoylbiliverdins are synthesized in 60%-87% yields from oxidation of dodeca-substituted porphyrins with NaNO2/TFA and air or by reaction with mCPBA/pyridine and air. The X-ray structures of two of the complexes and the electrochemistry of the three metallo-benzoylbiliverdins are discussed.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 4
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.145038104