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Spin canting in the 3D anionic dicyanamide structure (SPh(sub 3)Mn(dca)(sub 3) (Ph=phenyl, dca=dycyanamide)

Authors :
Schluter, John A.
Manson, Jamie L.
Hyzer, Kylee A.
Geiser, Urs
Source :
Inorganic Chemistry. July 12, 2004, Vol. 43 Issue 14, 4100-4102
Publication Year :
2004

Abstract

A new three dimensional anionic structure Mn(dca)(sub 3)(super -) [dca=dicyanamide, N(CN)2(super -) is crystallized by using SPh(sub3)(super +) (ph = phenyl) cation as molecular template. Result shows that this salt exhibits a spin canted antiferromagnet below T(sub N)=2.5 K with H(super SF)=0.6 T.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
14
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.145241044