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Reactions of (CF3)3BCO with amines and phosphines

Authors :
Finze, Maik
Bernhardt, Eduard
Willner, Helge
Lehmann, Christian W.
Source :
Inorganic Chemistry. Jan 23, 2006, Vol. 45 Issue 2, p669, 10 p.
Publication Year :
2006

Abstract

Reactions of the borane carbonyl (CF3)3BCO with selected amines and phosphines are studied. The exclusive attack at the carbonyl C atom is remarkable, although ligand exchange under release of CO is thermodynamically favored, as predicted by density functional theory calculations.

Subjects

Subjects :
Amines -- Analysis
Borane -- Chemical properties
Chemical reactions -- Analysis
Density functionals -- Analysis
Chemistry

Details

Language :
English
ISSN :
00201669
Volume :
45
Issue :
2
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.145243095

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