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MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid-base properties, proton transfer, and reversible protonolysis of sulfido ligands
- Source :
- Inorganic Chemistry. Jan 23, 2006, Vol. 45 Issue 2, p679, 9 p.
- Publication Year :
- 2006
-
Abstract
- The acid-base reactivity of MS2(dmpe)2, where M = Mo and W and dmpe = Me2PCH2CH2PMe2 is examined. Consistent with its ready protonation, complex M=Mo is methylated, and the use of excess MeOTf gives [MoS(OTf)(dmpe)2](super +) and Me2S in a rare example of double alkylation at a sulfido ligand.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 2
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.145243215