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Highly stable chiral cadmium 1,2,4-benzenetricarboxylate: Synthesis, structure, and NLO and fluorescence properties
- Source :
- Inorganic Chemistry. March 20, 2006, Vol. 45 Issue 6, 2474-2478
- Publication Year :
- 2006
-
Abstract
- A 3-D chiral cadmium coordination polymer [Cd2(OH)(1,2,4-BTC)] is prepared under hydrothermal conditions using an unsymmetrical 1,2,4-benzenetricarboxylate (1,2,4-BTC) and characterized by single crystal X-ray diffraction and the 1,2,4-BTC ligand is found to show an unprecedented coordination mode. The compound exhibits intense photoluminescence at room temperature and shows distinct NLO properties.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.146365106