Back to Search Start Over

Chiral layered zincophosphate [d-Co(en)3]Zn3([H.sub.0.5]PO4)3(HPO4)2 assembled about d-Co[(en).sub.3.sup.3+] complex cations

Authors :
Yu Wang
Peng Chen
Jiyang Li
Jihong Yu
Jin Xu
Qinhe Pan
Ruren Xu
Source :
Inorganic Chemistry. June 12, 2006, Vol. 45 Issue 12, p4764, 5 p.
Publication Year :
2006

Abstract

A new chiral layered zincophosphate [d-Co(en)3]Zn3[([H.sub.0.5]PO4)3[(HPO4)2 (ZnPO-CJ16) is hydrothermally synthesized by using the optically pure metal complex d-Co(en)3I3 as the template. The results reveal that symmetrical O...H...O H-bonds exist between inorganic sheets, which results in a pseudo-three-dimensional open-framework structure stabilized by strong H-bonds.

Details

Language :
English
ISSN :
00201669
Volume :
45
Issue :
12
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.148067502