Back to Search Start Over

Nitro group as a means of attaching organic molecules to silicon: Nitrobenzene on Si(100)-2*1

Authors :
Mendez De Leo, Lucila P.
Teplyakov, Andrew V.
Source :
Journal of Physical Chemistry B. April 6, 2006, Vol. 110 Issue 13, 6899-6905
Publication Year :
2006

Abstract

The computational and infrared studies of the reactions of nitrobenzene on a Si(100) surface which is a prototypical model reaction for understanding the behavior of bifunctional molecules on semiconductor surfaces is described. Computational exploration suggests that two stable structures could be formed and the initial reaction of nitrobenzene with the Si(100)-2*1 occurs through 1,3-dipolar cycloadditions of the nitro group to the silicon surface dimer.

Details

Language :
English
ISSN :
15206106
Volume :
110
Issue :
13
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.151406675