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PVTx measurements of the N-methylpyrrolidone/methanol mixed solvent: Cubic and SAFT EOS analyses

Authors :
Aparicio, Santiago
Garcia, Begona
Alcalde, Rafael
Davila, Maria J.
Leal, Jose M.
Source :
Journal of Physical Chemistry B. April 6, 2006, Vol. 110 Issue 13, 6933-6942
Publication Year :
2006

Abstract

The strongly nonideal behavior of the N-methylpyrrolidone (NMP) + methanol binary solvent was studied over the wide ranges of pressure and temperature. From the measured and derived excess properties, strong H-bonding is correlated with several cubic EOS, yielding inaccurate results with the most common equation of state (EOS) and very good data fitting with the Sako-Wu-Prausnitz equation.

Details

Language :
English
ISSN :
15206106
Volume :
110
Issue :
13
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.151406682