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Are the [NF4.sup.} cations in NF4BF4 really nontetrahedral?

Authors :
Haiges, Ralf
Gerken, Michael
Luga, Adriana
Bau, Robert
Christe, Karl O.
Source :
Inorganic Chemistry. Sept 18, 2006, Vol. 45 Issue 19, p7981, 4 p.
Publication Year :
2006

Abstract

The crystal structure of NF4BF4 was verified at different temperatures. The low-temperature X-ray structure and solid-state [.sup.19.F] MAS NMR spectra are in line with the conclusions reached from the vibrational spectra, that solid [NF4.sup.} salts contain only tetrahedral [NF4.sup.} cations.

Details

Language :
English
ISSN :
00201669
Volume :
45
Issue :
19
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.153497631