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B[F.sub.2] complex of fluorinated dipyrrolyldiketone: A new class of efficient receptor for acetate anions
- Source :
- Inorganic Chemistry. Oct 2, 2006, Vol. 45 Issue 20, p8205, 6 p.
- Publication Year :
- 2006
-
Abstract
- The preparation of the Beta-fluorinated derivative of the 1,3-dipyrrolyl-1,3-propanedione B[F.sub.2] complex from 3,4-difluoropyrrole and malonyl chloride, followed by treatment with B[F.sub.3].O[Et.sub.2] is presented. Results show that, despite the simple, acyclic, and neutral structure, the Beta-fluorinated derivative exhibits efficient 1:1 binding for anions in C[H.sub.2][Cl.sub.2] using the bridging CH and pyrrole NH as interaction sites.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 20
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.154178725