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B[F.sub.2] complex of fluorinated dipyrrolyldiketone: A new class of efficient receptor for acetate anions

Authors :
Maeda, Hiromitsu
Ito, Yoshihiro
Source :
Inorganic Chemistry. Oct 2, 2006, Vol. 45 Issue 20, p8205, 6 p.
Publication Year :
2006

Abstract

The preparation of the Beta-fluorinated derivative of the 1,3-dipyrrolyl-1,3-propanedione B[F.sub.2] complex from 3,4-difluoropyrrole and malonyl chloride, followed by treatment with B[F.sub.3].O[Et.sub.2] is presented. Results show that, despite the simple, acyclic, and neutral structure, the Beta-fluorinated derivative exhibits efficient 1:1 binding for anions in C[H.sub.2][Cl.sub.2] using the bridging CH and pyrrole NH as interaction sites.

Details

Language :
English
ISSN :
00201669
Volume :
45
Issue :
20
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.154178725