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Isocyanide and diisocyanide complexes of a tripalladium cluster

Authors :
Rashidi, Mehdi
Kristof, Eva
Vittal, Jagadese J.
Puddephatt, Richard J.
Source :
Inorganic Chemistry. March 30, 1994, Vol. 33 Issue 7, p1497, 5 p.
Publication Year :
1994

Abstract

Studies of tripalladium-cluster isocyanide and diisocyanide complexes reveal that a 42-electron configuration is formed with triply-bridging isocyanides. The complexes differ from platinum analogs that possess 44-electron configurations with terminal isocyanides. The nickel complexes have a 48-electron configuration with triply-bridging isocyanides. The NMR spectra reveal broad resonances for the Ch2P2 and ligand methyl resonances.

Details

ISSN :
00201669
Volume :
33
Issue :
7
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.15468339