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Magnetic exchange coupling in the FeIII6(mu6-O) core: a hint to the magnetic properties of higher-nuclearity spin clusters
- Source :
- Inorganic Chemistry. March 30, 1994, Vol. 33 Issue 7, p1559, 3 p.
- Publication Year :
- 1994
-
Abstract
- Studies of two hexairon(III) clusters containing a mu6-oxo bridge reveal that the unusual bridging mode causes weak antiferromagnetic exchange-coupling interactions between the metal centers with J trans and J cis values of 19(2) and 9(1) per cm, respectively. The studies may be useful in the search for magneto-structural correlations in oxo-bridged polyiron aggregates.
- Subjects :
- Iron compounds -- Research
Antiferromagnetism -- Analysis
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 33
- Issue :
- 7
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.15468359