Reactions of 1-aryl-1,2-dibromo-2-nitropropanes with 2-nitro-2-propyl anion in DMSO

Authors :: Bong, Rae Cho
Young Sung Suh
Seung Jae Lee
Eun Jeong Cho
Source :: Journal of Organic Chemistry. July 1, 1994, Vol. 59 Issue 13, p3681, 2 p.
Publication Year :: 1994
Abstract: Synthetic 1-aryl-1,2-dibromo-2-nitropropanes react with 2-propanenitronate in DMSO to yield 2-bromo-2-nitropropane and 2, 3-dimethyl-2,3-dinitrobutane. GC analyzes the products while cyclic voltammetry examines the redox properties of these compounds. High exothermicity of the reaction favors the ionic pathway in the reaction mechanism.

Subjects :: Nitrogen compounds -- Research
Anions -- Analysis
Biological sciences
Chemistry

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