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New skeletally stabilized silazanes and siloxazanes

Authors :
Prout, Timothy R.
Thompson, Martin L.
Haltiwanger, R. Curtis
Schaeffer, Riley
Norman, Arlan D.
Source :
Inorganic Chemistry. April 27, 1994, Vol. 33 Issue 9, p1778, 5 p.
Publication Year :
1994

Abstract

Siladiazoles are synthesized from reactions of 1,2(NH2)6C6H4 with equimolar MePhSiCl2 and Ph2SiCl2 in the presence of Et3N. Stereoselectivity is not observed in the reactions. Spectroscopy and X-ray crystallographic studies are used to characterize silazanes and siloxazanes. Comparisons of phosphazane and silazane systems show that intergroup interactions are less and different for silazane compounds.

Details

ISSN :
00201669
Volume :
33
Issue :
9
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.16029360