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Magnetic circular dichroism spectroscopic studies on the stereochemistry and coordination behavior of nickel porphyrins
- Source :
- Inorganic Chemistry. August 31, 1994, Vol. 33 Issue 18, p3873, 4 p.
- Publication Year :
- 1994
-
Abstract
- MCD spectroscopic studies of the electronic structures and coordination behaviors of three nickel porphyrins that have different patterns and amounts of macrocycle deformations reveals A-term peaks for all three compounds, indicating that both ruffled and saddle-shaped conformations retain D(2d) symmetry. MCD spectra of Ni(II) protoporphyrin IX-reconstituted hemoglobin ((Ni)Hb) and myoglobin ((Ni)Mb) reveal that protein does not influence the energy level of nickel porphyrins.
Details
- ISSN :
- 00201669
- Volume :
- 33
- Issue :
- 18
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.16376102