Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]-hydrogenase active site

Authors :: Justice, Aaron K.
Zampella, Giuseppe
De Gioia, Luca
Rauchfuss, Thomas B.
van der Vlugt, Jarl
Wilson, Scott R.
Source :: Inorganic Chemistry. March 5, 2007, Vol. 46 Issue 5, p1655, 10 p.
Publication Year :: 2007
Abstract: The degree of substitution that entails the use of chelating ligands is studied which stabilizes the complexes of the type [Fe-Fe]-hydrogenases. It is suggested that the dithiolato complexes with unsymmetrical coordination environments has led to a better understanding of the influence of the dithiolate on the stereochemistry of these complexes.

Subjects :: Thiols -- Structure
Thiols -- Chemical properties
Density functionals -- Usage
Binding sites (Biochemistry) -- Chemical properties
Binding sites (Biochemistry) -- Structure
Iron compounds -- Chemical properties
Iron compounds -- Structure
Chemistry

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