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Nucleophilicites of primary and secondary amines in water

Authors :
Brotzel, Frank
Ying Cheng Chu
Mayr, Herbert
Source :
Journal of Organic Chemistry. May 11, 2007, Vol. 72 Issue 10, p3679, 10 p.
Publication Year :
2007

Abstract

The kinetics of the reactions of various primary and secondary amines with the benzhydrylium ions in water are investigated, demonstrating their nucleophilcites. The results show a poor correlation between the nucleophilicities values, as the secondary alkyl amines and anilines are more nucleophilicdue to the difference in their pH values.

Details

Language :
English
ISSN :
00223263
Volume :
72
Issue :
10
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.165763291