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Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Authors :
Pohmakotr, Manat
Thamapipol, Sirinporn
Tuchinda, Patoomratana
Prabpai, Samran
Kongsaeree, Palangpon
Reutrakul, Vichai
Source :
Journal of Organic Chemistry. July 6, 2007, Vol. 72 Issue 14, p5418, 3 p.
Publication Year :
2007

Abstract

A general and convenient method for the synthesis of 2-(hydroxyalkyl)-5-methylenecyclopentenones through the Morita-Baylis-Hillman reaction of a masked 5-alkylidene-2-cyclopentenone followed by the flash vacuum pyrolysis of the resulting adduct is described.

Details

Language :
English
ISSN :
00223263
Volume :
72
Issue :
14
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.167331140