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Use of calyx[4]arenas in the redox chemistry of lanthanides: The reduction of dinitrogen by a calyx[4]arene-samarium complex

Authors :
Guillemot, Geoffroy
Castellano, Barbara
Pranje, Thierry
Solari, Euro
Floriani, Carlo
Source :
Inorganic Chemistry. June 25, 2007, Vol. 46 Issue 13, 5152-5154
Publication Year :
2007

Abstract

The synthesis and structural characterization of samarium-dinitrogen complex is described. The chemical and geometrical peculiarities of the electron rich environment provided by the calyx[4]arene dianion is expected to disfavor any low oxidation state of a metal.

Details

Language :
English
ISSN :
00201669
Volume :
46
Issue :
13
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.167765145