Back to Search
Start Over
Use of calyx[4]arenas in the redox chemistry of lanthanides: The reduction of dinitrogen by a calyx[4]arene-samarium complex
- Source :
- Inorganic Chemistry. June 25, 2007, Vol. 46 Issue 13, 5152-5154
- Publication Year :
- 2007
-
Abstract
- The synthesis and structural characterization of samarium-dinitrogen complex is described. The chemical and geometrical peculiarities of the electron rich environment provided by the calyx[4]arene dianion is expected to disfavor any low oxidation state of a metal.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 46
- Issue :
- 13
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.167765145