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Quinoxalino[2,3-b']porphyrin behave as [pi]-expanded porphyrins upon one-electron reduction: Broad control of the degree of delocalization through substitution at the macrocycle periphery
- Source :
- Journal of Physical Chemistry B. August 2, 2007, Vol. 111 Issue 30, 8762-8774
- Publication Year :
- 2007
-
Abstract
- The synthesis and redox properties of a series of free-base and metal(II) quinoxalino(2,3-b']porphyrins and their use in an investigation of the substituent effects on the degree of communication between the porphyrin and its [beta],[beta]'-fused quinoxalino component are reported.
Details
- Language :
- English
- ISSN :
- 15206106
- Volume :
- 111
- Issue :
- 30
- Database :
- Gale General OneFile
- Journal :
- Journal of Physical Chemistry B
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.167988130