Construction of [([[eta].sup.5]-[C.sub.5][Me.sub.5])Mo[S.sub.3][Cu.sub.3]]-based supramolecular assemblies from the [[([[eta].sub.5]-[C.sub.5][Me.sub.5])Mo[S.sub.3][(CuNCS).sub.3]].sup.-] cluster anion and multitopic ligands with different symmetries

The effects of ligand symmetry on the rational design and construction of Mo/Cu/S cluster-based supramolecular arrays are analyzed. The results have shown that the formation of the four different multidimensional topological structures is affected by the symmetry of the multitopic ligands.