Synthesis, structures, and magnetic properties of Fe2, Fe17, and Fe19 Oxo-bridged iron clusters: the stabilization of high ground state spins by cluster aggregates

Study of the magnetic properties of the synthesized compound (Fe(heidi)(H2O))2 by the alternating current and direct current susceptibility measurements reveals that the clusters have a ground state spin of less than 33/2. The compound crystallizes in a triclinic space group with different crystallographic parameters. Experimental data reveal that the (Fe(heidi)(H2O))2 is a dinuclear iron(III) compound in which two iron atoms are attached to each other by an alkoxide function.