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2-Amino-7-nitro-fluorenes in neat and mixed solvents-optical band shapes and solvatochromism

Authors :
Karunakaran, Venugopal
Senyushkina, Tamara
Saroja, Ginagunta
Liebscher, Jurgen
Ernsting, Nikolaus P.
Source :
Journal of Physical Chemistry A. Nov 1, 2007, Vol. 111 Issue 43, 10944-10952
Publication Year :
2007

Abstract

Femtosecond transient absorption spectroscopy of amino-nitro-fluorenes in the ultraviolet (UV)-visible range has shown that the dynamic Stokes shift of the emission band is sensitive to infrared-active modes of the solvent. The solvatochromic plots have differed significantly from those that use peak positions of absorption spectra and fluorescence quantum distributions.

Details

Language :
English
ISSN :
10895639
Volume :
111
Issue :
43
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.172938834